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Physical aging and charge transport in poly(3‐hexylthiophene)
Author(s) -
Duzhko Volodimyr V.
Publication year - 2016
Publication title -
physica status solidi (a)
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.532
H-Index - 104
eISSN - 1862-6319
pISSN - 1862-6300
DOI - 10.1002/pssa.201532307
Subject(s) - charge (physics) , materials science , amorphous solid , chemical physics , charge carrier , phase transition , phase (matter) , activation energy , electron mobility , condensed matter physics , chemistry , crystallography , optoelectronics , physics , organic chemistry , quantum mechanics
The bulk charge transport in a series of regioregular poly(3‐hexylthiophene) materials with different molecular weights (MW) has been studied by the time‐of‐flight technique. Three distinct temperature regions with transitions at ∼60 and ∼140 °C in lower MW material (9.6 kDa), and four regions with an additional transition at ∼180 °C in higher MW material (32.3 kDa) are identified in the temperature dependence of charge carrier mobility and the origin of these transitions is discussed. A pronounced effect of physical aging which reveals as a reversible increase of charge mobility is found. Densification of amorphous phase in‐between the nanocrystals, which reduces the potential energy barriers and provides larger charge transfer integrals, is proposed as an origin of the effect.