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Synthesis of location‐dependent phosphorus‐doped ZnO nanostructures on the porous alumina membranes
Author(s) -
Hu Dazhi,
Fan Donghua,
Zhu Yufu,
Wang Wei,
Pan Fengming,
Wu Ping,
Fan Jiyu
Publication year - 2014
Publication title -
physica status solidi (a)
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.532
H-Index - 104
eISSN - 1862-6319
pISSN - 1862-6300
DOI - 10.1002/pssa.201330159
Subject(s) - raman spectroscopy , nanorod , materials science , nanostructure , membrane , doping , chemical engineering , zinc , substrate (aquarium) , phosphorus , crystal structure , nanotechnology , crystallography , chemistry , metallurgy , biochemistry , physics , oceanography , optoelectronics , engineering , geology , optics
Phosphorus‐doped ZnO nanostructures are synthesized on porous alumina membranes by evaporating the mixture of pure Zn, carbon, and P 2 O 5 powder. The influences of growth area on phosphorus‐doped ZnO nanostructures are studied in detail. The Raman spectra indicate that phosphorus enters into the ZnO crystal lattice to easily form a Zn–P bond and/or a P Zn –O one by occupying an O site and a Zn one. The further analyses for Raman spectra and SEM results display that the change of nanorods morphology should mainly be attributed to the relaxation of lattice strain caused by P occupying Zn sites. Compared with the morphology of samples on Si substrate, it is found that alumina membranes are helpful to the growth of nanostructures due to the existence of localized negative charges. The growth mechanism of different nanostructures is also discussed. The present research results are helpful to realize the preparation of phosphorus‐doped ZnO nanostructures with controllable morphologies.