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Low temperature growth of nanocrystalline and ultrananocrystalline diamond films: A comparison
Author(s) -
Kulisch Wilhelm,
Petkov Christo,
Petkov Emil,
Popov Cyril,
Gibson P. Neil,
Veres Miklos,
Merz Rolf,
Merz Birgit,
Reithmaier Johann Peter
Publication year - 2012
Publication title -
physica status solidi (a)
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.532
H-Index - 104
eISSN - 1862-6319
pISSN - 1862-6300
DOI - 10.1002/pssa.201228270
Subject(s) - x ray photoelectron spectroscopy , chemical vapor deposition , materials science , raman spectroscopy , nanocrystalline material , diamond , carbon film , micrometer , chemical engineering , atmospheric temperature range , deposition (geology) , analytical chemistry (journal) , thin film , nanotechnology , composite material , chemistry , optics , organic chemistry , paleontology , physics , meteorology , biology , sediment , engineering
Abstract In this paper the low temperature deposition of nanocrystalline and ultrananocrystalline diamond (UNCD) films is compared and discussed. NCD films were prepared by hot filament chemical vapor deposition from a 1% CH 4 /H 2 mixture, while microwave plasma chemical vapour deposition was used to deposit UNCD films from a mixture of 17% CH 4 /N 2 . The resulting films have been thoroughly characterized concerning their morphology and structure by scanning electron microscopy and concerning their crystalline properties by X‐ray diffraction. The composition was analyzed by X‐ray photoelectron spectroscopy (XPS), whereas XPS and Raman spectroscopy were applied to get information on the bonding structure of the films. The most important result of this study is that the composition, structure, morphology, and bonding environment of UNCD hardly change if the deposition temperature is lowered from 770 to 530 °C or even 450 °C. In contrast, there are drastic changes of the nature of NCD films if the temperature is reduced to 700 °C or even lower. Interestingly, the sp 2 /sp 3 ratio of the NCD films remains low and constant in the temperature range investigated. Rather, the nature of the sp 2 grain boundary material undergoes drastic changes if the temperature is lowered below 700 °C. In addition, the films become inhomogeneous on a micrometer (not nanometer) scale. Possible reasons for these observations will be discussed throughout the paper.