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Nanosheet‐based BiVO 4 hierarchical microspheres and their photocatalytic activity under visible light
Author(s) -
Li JunQi,
Wang DeFang,
Liu Hui,
Du Juan,
Zhu ZhenFeng
Publication year - 2012
Publication title -
physica status solidi (a)
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.532
H-Index - 104
eISSN - 1862-6319
pISSN - 1862-6300
DOI - 10.1002/pssa.201127236
Subject(s) - photocatalysis , materials science , mesoporous material , specific surface area , nanosheet , hydrothermal circulation , chemical engineering , adsorption , nanostructure , visible spectrum , nanotechnology , band gap , catalysis , optoelectronics , chemistry , organic chemistry , engineering
Abstract Hierarchical BiVO 4 microspheres assembled by nanosheets were synthesized by hydrothermal process under microwave irradiation. The morphology and compositional characteristics of the BiVO 4 architectures were investigated by SEM, TEM, and XRD. The possible formation mechanism for the architectures was discussed. UV–vis diffuse reflectance spectra indicated the BiVO 4 hierarchical microspheres had absorption in both UV and vis light areas. The specific surface area and porosity of the BiVO 4 architectures were investigated by using nitrogen adsorption and desorption isotherms. Because of the narrow bandgap and the novel micro‐/nanostructure, the BiVO 4 architectures show a more excellent photocatalytic activity under visible light irradiation than the BiVO 4 solid microspheres and P25. Several possible reasons for the higher photocatalytic activity have been taken into consideration, namely, high specific surface area, hierarchical mesoporous structure, and quantum size effect. In addition, the photocatalyst is stable during the reaction and can be used repeatedly.