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Laplace Meyer–Neldel relation
Author(s) -
Okamoto Hiroaki,
Sobajima Yasushi,
Toyama Toshihiko,
Matsuda Akihisa
Publication year - 2010
Publication title -
physica status solidi (a)
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.532
H-Index - 104
eISSN - 1862-6319
pISSN - 1862-6300
DOI - 10.1002/pssa.200982657
Subject(s) - laplace transform , reciprocal , analogy , representation (politics) , context (archaeology) , relation (database) , domain (mathematical analysis) , mathematics , mathematical analysis , two sided laplace transform , statistical physics , physics , computer science , paleontology , philosophy , linguistics , database , politics , political science , law , biology , fourier analysis , fourier transform , fractional fourier transform
Universal Meyer–Neldel (MN) relations in the reciprocal temperature domain are derived on the basis of Laplace transform representation of thermally activated quantities, by a mathematical analogy to the generalized Kramers–Kronig relations in the frequency domain. We concern the circumstances that allow the MN rule to be experimentally observed in realistic physical systems within the context of the Fano resonant‐transition model incorporating Yelon's multi‐excitation concept.