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The in‐plane magnetic anisotropy of RF‐sputtered FeNiN thin films
Author(s) -
Wang X. F.,
Wu P.,
Liu X. J.,
Chen X. S.,
Li Z. Q.,
Bai H. L.,
Jiang E. Y.
Publication year - 2008
Publication title -
physica status solidi (a)
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.532
H-Index - 104
eISSN - 1862-6319
pISSN - 1862-6300
DOI - 10.1002/pssa.200723090
Subject(s) - anisotropy , nitrogen , materials science , thin film , magnetic anisotropy , phase (matter) , sputtering , sputter deposition , analytical chemistry (journal) , condensed matter physics , nuclear magnetic resonance , chemistry , nanotechnology , magnetic field , magnetization , optics , physics , organic chemistry , chromatography , quantum mechanics
FeNiN thin films were synthesized on Si(100) substrates at room temperature by RF magnetron sputtering. The nitrogen concentration dependence of their phase structure and magnetic properties was systematically investigated. With increasing nitrogen partial pressure ( P N 2), the FeNiN thin films successively showed a α‐Fe phase at P N 2≤ 5.0%, then a pure ε‐Fe 3 N phase at P N 2= 25.0%, and then a ζ‐(Fe,Ni) 2 N phase at P N 2= 25.0%, but there was no γ′‐(Fe,Ni) 4 N phase in the whole P N 2range. These films with various phases presented different magnetic properties, which can be ascribed to the strong effects of nitrogen content. The optimum soft magnetic properties with M s of ∼1721 emu/cm 3 and H C of <4 Oe were obtained at P N 2= 3.0% at room temperature. In particular, we experimentally found that the nitrogen atoms play a key role in controlling the in‐plane magnetic anisotropy, and the evolution of the in‐plane anisotropy derives from the combined effects of internal stress, shape anisotropy, and induced anisotropy. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)