Cyclic oligomers of oxetane‐based dipeptide isosteres derived from  L ‐rhamnose | Zendy

Fleet George W. J. | Zendy; Johnson Stephen W. | Zendy; Jones John H. | Zendy

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Cyclic oligomers of oxetane‐based dipeptide isosteres derived from L ‐rhamnose

Author(s) -

Fleet George W. J.,

Johnson Stephen W.,

Jones John H.

Publication year - 2006

Publication title -

journal of peptide science

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.475

H-Index - 66

eISSN - 1099-1387

pISSN - 1075-2617

DOI - 10.1002/psc.759

Subject(s) - oxetane , dipeptide , chemistry , rhamnose , stereochemistry , organic chemistry , amino acid , biochemistry , polysaccharide

Two new cyclic oligomers, cyclo‐tetra‐[2,4‐anhydro‐3‐ O ‐ tert ‐butyldimethylsilyl‐5‐deoxy‐ L ‐rhamnonamido‐( N →5)] and the corresponding 6‐deoxy‐ D ‐gulonate cyclic ‘tetramer’, have been synthesised from linear tetrameric oligomers, using TBTU‐ and pentafluorophenyl ester–based methodologies, respectively. These two compounds constitute a novel class of cyclic oligomers derived from oxetane‐based sugar amino acids. Copyright © 2006 European Peptide Society and John Wiley & Sons, Ltd.

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