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Synthesis of a New 1,2,4‐Triazine Derived Azidoxime
Author(s) -
Cleveland Alexander H.,
Imler Gregory H.,
Snyder Christopher J.,
Chavez David E.,
Parrish Damon A.
Publication year - 2022
Publication title -
propellants, explosives, pyrotechnics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.56
H-Index - 65
eISSN - 1521-4087
pISSN - 0721-3115
DOI - 10.1002/prep.202200138
Subject(s) - detonation , explosive material , triazine , detonation velocity , diffraction , sodium azide , materials science , single crystal , energetic material , ethanol , 1,3,5 triazine , crystallography , chemistry , analytical chemistry (journal) , polymer chemistry , organic chemistry , optics , physics
A 1,2,4‐triazine based azidoxime was formed via the substitution of a chloroxime ( 3 ) with sodium azide in ethanol. This compound was characterized via single‐crystal X‐ray diffraction. This material has a calculated density of 1.746 g ⋅ cm −3 and is less sensitive to impact, spark, and friction, as compared to PETN and RDX. The dehydrated material has a calculated density of 1.823 g ⋅ cm −3 and the detonation pressure and velocity of 4 are calculated to be 29.1 GPa and 8.67 km ⋅ s −1 , respectively.