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Synthesis and Characterization of the Energetic 3‐Azido‐5‐amino‐6‐nitro‐1,2,4‐triazine
Author(s) -
Creegan Shan E.,
Zeller Matthias,
Byrd Edward F. C.,
Piercey Davin G.
Publication year - 2021
Publication title -
propellants, explosives, pyrotechnics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.56
H-Index - 65
eISSN - 1521-4087
pISSN - 0721-3115
DOI - 10.1002/prep.202000136
Subject(s) - nitro , triazine , energetic material , chemistry , 1,3,5 triazine , crystal structure , single crystal , characterization (materials science) , combinatorial chemistry , crystallography , polymer chemistry , materials science , organic chemistry , nanotechnology , explosive material , alkyl
The reaction of diazotetrazole with nitroacetonitrile led to the isolation of the simple 1,2,4‐triazine‐based energetic 3‐azido‐5‐amino‐6‐nitro‐1,2,4‐triazine. It and related compounds were chemically characterized by NMR, IR, and single‐crystal X‐ray crystallography. Their energetic sensitivities (impact, friction) were experimentally determined and energetic performances calculated. The ability of 3‐azido‐5‐amino‐6‐nitro‐1,2,4‐triazine to form N ‐oxides was also studied.