Premium
Nitration of Acyl Derivatives of 2,4,6,8,10,12‐Hexaazaisowurtzitane
Author(s) -
Kalashnikov Alexander I.,
Sysolyatin Sergey V.,
Surmachev Vladimir N.
Publication year - 2019
Publication title -
propellants, explosives, pyrotechnics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.56
H-Index - 65
eISSN - 1521-4087
pISSN - 0721-3115
DOI - 10.1002/prep.201900149
Subject(s) - nitration , formic acid , chemistry , nitro , nitric acid , organic chemistry , medicinal chemistry , alkyl
In this paper, we studied the nitration of 2,4,6,8,10,12‐hexaazaisowurtzitane acyl derivatives with mixed H 2 SO 4 /HNO 3 and HNO 3 /NH 4 NO 3 . The substitution of the nitro group for acyl residues of weaker acids took place most easily. The nitration of such amides in the mixed acid proceeded fairly good. In the case of using amides of formic and other stronger acids, the best results were achieved with HNO 3 /NH 4 NO 3 .