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Solid+Solid=Liquid: An ON‐Switch for Sensitivity in Deep Eutectic Solvents?
Author(s) -
Ahmed Yonis,
Quintana Ashlee,
Warmoth Gregory,
Deplazes Stephan,
Brand Adam,
Mills Jeffrey,
Schneider Stefan
Publication year - 2019
Publication title -
propellants, explosives, pyrotechnics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.56
H-Index - 65
eISSN - 1521-4087
pISSN - 0721-3115
DOI - 10.1002/prep.201900120
Subject(s) - eutectic system , explosive material , melting point , propellant , intermolecular force , ionic liquid , solvent , deep eutectic solvent , materials science , salt (chemistry) , volatility (finance) , chemical engineering , eutectic bonding , melting point depression , chemistry , organic chemistry , molecule , metallurgy , alloy , economics , financial economics , engineering , catalysis
Deep Eutectic Solvents show the low volatility/toxicity of “classical” Ionic Liquids. The formation of a Deep Eutectic Solvent from two solids is the result of intermolecular bonds being weakened or broken and rearranged in completely new networks. The effect of these new bonding arrangements on physical properties like melting point, thermal stability, density, viscosity, and impact sensitivity of some binary mixtures of energetic nitrate salt and nitrogen containing ligands was investigated. With some exceptions the liquids showed increased sensitivity compared to their solid ingredients, which suggest that this might provide an ON‐switch for sensitivity. Furthermore, applying the Deep Eutectic Solvent concept to propellant and explosive development may allow incorporation of established energetic solids into liquid applications.