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Propellants Reactivity Enhancement with Nanothermites
Author(s) -
Berthe JeanEdouard,
Comet Marc,
Schnell Fabien,
Suma Yves,
Spitzer Denis
Publication year - 2016
Publication title -
propellants, explosives, pyrotechnics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.56
H-Index - 65
eISSN - 1521-4087
pISSN - 0721-3115
DOI - 10.1002/prep.201600029
Subject(s) - propellant , combustion , materials science , flash point , ignition system , composite material , autoignition temperature , burn rate (chemistry) , explosive material , analytical chemistry (journal) , chemical engineering , chemistry , aerospace engineering , chromatography , organic chemistry , engineering
Propellant grains (Vectan A1) were coated with a thin and stable layer (50 μm, 10 wt‐%) of a “green” sulfate‐based nanothermite (Na 2 SO 4 /Al). This flash composition was used herein as an internal pyrotechnic lighter to accelerate the ignition and the combustion of the propellant. The combustion of the modified propellant, which was tested in one‐end open tubes, propagates four orders of magnitude faster than the one of pristine Vectan A1. This tremendous effect was tuned by varying the proportion of coated Vectan A1 grains from 20 to 100 % in the samples. The percolation threshold is in between 20 and 40 %. Beyond this point, the effect can be improved by increasing the proportion of nanothermite‐coated propellant grains in the charge.