Premium
Synthesis, Crystal Structure, and Thermal Behaviors of 3‐Nitro‐1,5‐bis(4,4′‐dimethylazide)‐1,2,3‐triazolyl‐3‐azapentane (NDTAP)
Author(s) -
Wang Yinglei,
Xu Kangzhen,
Zhao Fengqi,
Ji Yueping,
Yi Jianhua,
Xu Siyu,
Gao Fulei,
Chen Bin
Publication year - 2013
Publication title -
propellants, explosives, pyrotechnics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.56
H-Index - 65
eISSN - 1521-4087
pISSN - 0721-3115
DOI - 10.1002/prep.201200146
Subject(s) - monoclinic crystal system , thermal decomposition , azide , thermal stability , crystal structure , energetic material , chemistry , decomposition , nitro , elemental analysis , isothermal process , thermal analysis , crystallography , proton nmr , single crystal , mass spectrometry , thermal , stereochemistry , inorganic chemistry , organic chemistry , explosive material , alkyl , physics , chromatography , meteorology , thermodynamics
Abstract The energetic material, 3‐nitro‐1,5‐bis(4,4′‐dimethyl azide)‐1,2,3‐triazolyl‐3‐azapentane (NDTAP), was firstly synthesized by means of Click Chemistry using 1,5‐diazido‐3‐nitrazapentane as main material. The structure of NDTAP was confirmed by IR, 1 H NMR, and 13 C NMR spectroscopy; mass spectrometry, and elemental analysis. The crystal structure of NDTAP was determined by X‐ray diffraction. It belongs to monoclinic system, space group C 2/ c with crystal parameters a =1.7285(8) nm, b =0.6061(3) nm, c =1.6712(8) nm, β =104.846(8)°, V =1.6924(13) nm 3 , Z =8, μ =0.109 mm −1 , F (000)=752, and D c =1.422 g cm −3 . The thermal behavior and non‐isothermal decomposition kinetics of NDTAP were studied with DSC and TG‐DTG methods. The self‐accelerating decomposition temperature and critical temperature of thermal explosion are 195.5 and 208.2 °C, respectively. NDTAP presents good thermal stability and is insensitive.