Premium
Preparation of Magnesium‐based Hydrogen Storage Materials and Their Effect on the Thermal Decomposition of Ammonium Perchlorate
Author(s) -
Liu Leili,
Xin Jingjing,
Ma Feng,
Zhi Chunlei,
Li Fengsheng
Publication year - 2013
Publication title -
propellants, explosives, pyrotechnics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.56
H-Index - 65
eISSN - 1521-4087
pISSN - 0721-3115
DOI - 10.1002/prep.201200120
Subject(s) - hydrogen storage , ammonium perchlorate , thermal decomposition , magnesium , decomposition , hydrogen , inorganic chemistry , chemistry , materials science , monoclinic crystal system , thermal analysis , crystal structure , thermal , metallurgy , organic chemistry , physics , meteorology
Magnesium‐based hydrogen storage materials (MgH 2 , Mg 2 NiH 4 , and Mg 2 Cu‐H) were prepared and their structures were determined by XRD and ICP investigations. Mg 2 NiH 4 has a monoclinic crystal structure and Mg 2 Cu‐H is a mixture of MgCu 2 and MgH 2 . The effects of magnesium‐based hydrogen storage materials on the thermal decomposition of ammonium perchlorate (AP) were studied by thermal analysis (DSC). It was found that magnesium‐based hydrogen storage materials show obvious boosting effects on the thermal decomposition of AP. The thermal decomposition peak temperature of AP was decreased, while the heat release of the decomposition of AP was increased. It was revealed that the effects of magnesium‐based hydrogen storage materials on the decomposition of AP become stronger with increasing content. The influence mechanism on the thermal decomposition of AP is suggested as follows: hydrogen released from magnesium‐based hydrogen storage materials and Mg, Ni, or Cu react with the decomposed products of AP.