The Synthesis and Energetic Properties of 5,7‐Dinitrobenzo‐1,2,3,4‐tetrazine‐1,3‐dioxide (DNBTDO) | Zendy

Klapötke Thomas M. | Zendy; Piercey Davin G. | Zendy; Stierstorfer Jörg | Zendy; Weyrauther Michael | Zendy

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The Synthesis and Energetic Properties of 5,7‐Dinitrobenzo‐1,2,3,4‐tetrazine‐1,3‐dioxide (DNBTDO)

Author(s) -

Klapötke Thomas M.,

Piercey Davin G.,

Stierstorfer Jörg,

Weyrauther Michael

Publication year - 2012

Publication title -

propellants, explosives, pyrotechnics

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.56

H-Index - 65

eISSN - 1521-4087

pISSN - 0721-3115

DOI - 10.1002/prep.201100151

Subject(s) - tetrazine , materials science , thermal stability , yield (engineering) , sensitivity (control systems) , grain size , composite material , chemistry , organic chemistry , electronic engineering , engineering

Energetic tetrazine‐1,3‐dioxide, 5,7‐dinitrobenzo‐1,2,3,4‐tetrazine‐1,3‐dioxide ( DNBTDO ), was synthesized in 45 % yield. DNBTDO was characterized as an energetic material in terms of performance ( V det 8411 m s −1 ; p CJ 3.3×10 10 Pa at a density of 1.868 g cm −3 ), mechanical sensitivity (impact and friction as a function of grain size), and thermal stability ( T dec 204 °C). DNBTDO exhibits a sensitivity slightly higher than that of RDX , and a performance slightly lower (96 % of RDX ).

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