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Thermal Decomposition of Aminonitrobenzodifuroxan
Author(s) -
Zhang Wei,
Luo Yunjun,
Li Jie,
Li Xiaomeng
Publication year - 2008
Publication title -
propellants, explosives, pyrotechnics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.56
H-Index - 65
eISSN - 1521-4087
pISSN - 0721-3115
DOI - 10.1002/prep.200800217
Subject(s) - thermal decomposition , decomposition , fourier transform infrared spectroscopy , diffractometer , differential scanning calorimetry , chemistry , molecule , activation energy , analytical chemistry (journal) , crystallography , organic chemistry , crystal structure , physics , thermodynamics , quantum mechanics
In this study, the thermal decomposition properties of aminonitrobenzodifuroxan are studied using a differential scanning calorimeter (DSC), a thermogravimeter (TG), an X‐ray diffractometer, a mass spectrometer (MS), and a Fourier transform infrared spectrometer (FTIR). The results demonstrate that aminonitrobenzodifuroxan undergoes thermal decomposition in the solid state. Under elevated temperatures, the decomposition primarily involves two steps: separation of nitro group and ring‐scission of the furoxan circles at 198.1 °C, and decomposition of the relatively stable residues (benzofuroxan circle) at 199.1 °C. Moreover, it is found that among the products, nitrogen dioxide undergoes oxidation and catalysis on the host molecule during the whole decomposition. Based on Kissinger and Ozawa functions, we deduce that the activation energies of these two reactions are 167.68 and 204.55 kJ mol −1 , respectively. The released energy (Δ H ) of CL‐18 is −1781.8 J g −1 .