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Study on the Nitrolysis of Hexamethylenetetramine by NMR Spectrometry . Part III: The NMR spectral data of some products and intermediates from the nitrolysis of HA
Author(s) -
Fang Zhijie,
Chen Ju,
Li Fuping
Publication year - 1997
Publication title -
propellants, explosives, pyrotechnics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.56
H-Index - 65
eISSN - 1521-4087
pISSN - 0721-3115
DOI - 10.1002/prep.19970220603
Subject(s) - hexamethylenetetramine , methylene , chemistry , chemical shift , nitric acid , mass spectrometry , organic chemistry , chromatography
The 1 H and 13 C chemical shifts of methylene groups in nitric acid are reported for seven products and intermediates involved in the formation of 1,3,5‐trinitro‐1,3,5‐triazacyclohexane (RDX) from the nitrolysis of hexamethylenetetramine (HA). Based on the results, the 1 H and 13 C chemical shift ranges of the methylene groups in different kinds of methylenenitramines from the nitrolysis liquors of HA were discussed.