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A Study of Some Charge‐Transfer Complexes of 2‐methyl‐1,3,6,8‐tetranitronaphthalene
Author(s) -
Cuming S.,
Wells C. H. J.
Publication year - 1996
Publication title -
propellants, explosives, pyrotechnics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.56
H-Index - 65
eISSN - 1521-4087
pISSN - 0721-3115
DOI - 10.1002/prep.19960210109
Subject(s) - charge (physics) , acceptor , chemistry , electron acceptor , range (aeronautics) , electron transfer , electron , conduction electron , conduction band , electron donor , thermal conduction , photochemistry , materials science , physics , organic chemistry , catalysis , condensed matter physics , quantum mechanics , composite material
Charge‐transfer complexes have been prepared with 2‐methyl‐1,3,6,8‐tetranitronaphthalene ( I ) as electron acceptor and various 9‐substituted anthracenes as electron donor. The electron affinity of ( I ) has been determined as 1.12 ± 0.07 eV, and the energy of activation for conduction in the complexes studied lie in the range 0.27 eV–0.74 eV.