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Aminotetryls: Synthesis, spectral characterization, thermal decomposition and explosive properties
Author(s) -
Hutchinson C. D.,
Krishna Mohan V.,
Millar R. W.
Publication year - 1984
Publication title -
propellants, explosives, pyrotechnics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.56
H-Index - 65
eISSN - 1521-4087
pISSN - 0721-3115
DOI - 10.1002/prep.19840090504
Subject(s) - explosive material , chemistry , thermal decomposition , steric effects , thermal stability , infrared spectroscopy , decomposition , analytical chemistry (journal) , organic chemistry
This paper describes the synthesis and spectral investigations of two amino derivatives of N‐methyl‐N‐(2,4,6‐trinitrophenyl)nitramine (tetryl). Also discussed are the results from thermal decomposition studies on the three explosives, viz. tetryl, 3‐aminotetryl (3 AT) and 3,5‐diaminotetryl (3,5 DAT) and preliminary work on the explosive properties of the last two compounds. The aminotetryls have been prepared by the amination of the corresponding chlorotetryls. The yield was 87% for 3 AT, but was only 33% for 3,5 DAT, probably due to steric crowding around the benzene nucleus. The mass spectra show interesting differences in the electron impact fragmentation patterns of the three tetryls with the M + ion relative intensities following the order 3,5 DAT > 3 AT > tetryl, which could be due to (a) resonance stabilization and (b) hydrogen bonding effects. Evidence for the latter is also found in the infrared spectra of these compounds. Arrhenius kinetic parameters derived from thermal decomposition studies of the three compounds are presented and show that 3,5 DAT is thermally less stable than 3 AT. Explosive sensitiveness tests indicate that the diamino compound is the most sensitive, the trend being 3,5 DAT > 3 AT > tetryl. This is contrary to the generally found desensitizing influence of NH 2 groups on the thermal stability and explosive sensitiveness of trinitroaromatic energetic molecules. Mechanisms to account for the observed thermal decomposition behaviour and explosive sensitiveness patterns are discussed.