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On the Detonation Characteristics of CHNO‐Type Condensed Explosives. A parameter study
Author(s) -
Swaminathan V.,
Rajagopalan S.
Publication year - 1982
Publication title -
propellants, explosives, pyrotechnics
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.56
H-Index - 65
eISSN - 1521-4087
pISSN - 0721-3115
DOI - 10.1002/prep.19820070202
Subject(s) - explosive material , detonation , volume (thermodynamics) , parametric statistics , thermodynamics , mechanics , detonation velocity , chemistry , materials science , physics , mathematics , statistics , organic chemistry
Abstract The object of the present paper is to carry out a parametric study which takes into consideration the variations of the detonation characteristics such as CJ pressure, CJ temperature, velocity of detonation (VOD), and gas volume of CHNO‐based condensed explosive systems in connection with the changes in input parameters like loading density and heat of formation of the explosive in question. Meaningful equations which describe adequately the interrelationships between the parameters were derived for a typical CHNO‐type explosive. The study is likely to be of considerable help in determining the variations in the magnitudes of the detonation parameters corresponding to a given change in the relevant input characteristics. The results of such studies should also be important in estimating the uncertainty of a parameter, like VOD, arising from the uncertainty in the heat of formation of the explosive which is often determined experimentally and whose values is often of questionable validity. The principal features that emerge from the investigations in this paper are: (1) while CJ pressure and VOD tend to increase sizably with the loading density of the explosive, CJ temperature and CJ volume decrease with an increase in the loading density; and (2) all the four parameters, viz., CJ pressure, CJ temperature, VOD, and CJ volume increase, however, being of a marginal nature, barring the CJ temperature whose variations with the heat of formation are not insignificant.

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