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3D Arrangement of Magnetic Particles in Thin Polymer Films Assisted by Magnetically Patterned Exchange Bias Layer Systems
Author(s) -
Koch Iris,
Langner Markus,
Holzinger Dennis,
Merkel Maximilian,
Reginka Meike,
Huhnstock Rico,
Tomiţa Andreea,
Jauregui Caballero Claudia,
Greiner Andreas,
Ehresmann Arno
Publication year - 2021
Publication title -
particle and particle systems characterization
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.877
H-Index - 56
eISSN - 1521-4117
pISSN - 0934-0866
DOI - 10.1002/ppsc.202100072
Subject(s) - materials science , polydimethylsiloxane , polymer , magnetic nanoparticles , superparamagnetism , substrate (aquarium) , layer (electronics) , particle (ecology) , magnetic anisotropy , nanoparticle , composite material , polyvinyl alcohol , nanotechnology , magnetic field , magnetization , oceanography , physics , quantum mechanics , geology
Abstract The possibility to arrange and embed magnetic micro‐ and nanoparticles in thin polymer film systems using flat magnetically patterned substrate templates is investigated. In contrast to self‐organized particle rows forming by applying a homogeneous magnetic field, particles adapt to the magnetic field landscape of the substrate's magnetic pattern prior to polymer crosslinking. Crosslinking then fixes the particle positions in the polymer. The process is tested for composites of hydrophobic polydimethylsiloxane (PDMS) and maghemite nanoparticles as well as for hydrophilic polyvinyl alcohol (PVOH) and hydrophilic functionalized, superparamagnetic core–shell microspheres. The substrate template is an exchange bias layer system magnetically patterned into parallel‐stripe domains with in‐plane magnetizations and head‐to‐head/tail‐to‐tail remanent magnetization orientation in adjacent magnetic domains. A high occupancy percentage of magnetic beads on a domain wall as well as anisotropic actuation of the composite is achieved.