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Robust and Flexible Colloidal Photonic Crystal Films with Bending Strain–Independent Structural Colors for Anticounterfeiting
Author(s) -
Pan Mengyao,
Li Xiao bai,
Xiong Chengjia,
Chen Xiaoyi,
Wang Lebin,
Chen Xi,
Pan Lei,
Xu Hongbo,
Zhao Jiupeng,
Li Yao
Publication year - 2020
Publication title -
particle and particle systems characterization
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.877
H-Index - 56
eISSN - 1521-4117
pISSN - 0934-0866
DOI - 10.1002/ppsc.201900495
Subject(s) - structural coloration , materials science , bending , colloid , photonics , flexible display , nanotechnology , ethylene glycol , photonic crystal , composite material , optoelectronics , chemical engineering , layer (electronics) , thin film transistor , engineering
Colloidal photonic crystals (PCs) possess iridescent and metallic structural color, making them an attractive candidate for anticounterfeiting. However, traditional colloidal PC‐based anticounterfeiting materials usually have bending‐induced color‐switching characteristics or poor flexible stability, significantly affecting their color reproducibility and durability. Here, a novel robust colloidal PC film with bending strain–independent structural color and high flexible stability has been developed through the self‐assembly of SiO 2 particles into the poly(ethylene glycol) diacrylate (PEGDA) matrix. The unique microstructure of the colloidal PC film contains ordered and disordered arrays of SiO 2 nanoparticles embedded into the flexible PEGDA matrix, which is crucial to achieving bending strain–independent structural color. In fact, during the bending process, the colorless disordered arrays act as the buffer space, avoiding deformation of the colored ordered arrays and thus maintaining its original structural color. Remarkably, the film retains its structural and optical integrity after 10 000 times bending, supporting its high flexible stability and robustness. In addition, the film shows high transparency so that it can easily achieve an invisible and visible state transition under switch of weak and strong light. The film is potentially useful for applications in anticounterfeiting and encryption.