Premium
Proof‐of‐Concept Studies Directed toward the Formation of Metallic Ag Nanostructures from Ag 3 PO 4 Induced by Electron Beam and Femtosecond Laser
Author(s) -
dos Santos Clayane Carvalho,
Assis Marcelo,
Machado Thales Rafael,
dos Santos Pereira Paula Fabiana,
MinguezVega Gladys,
Cordoncillo Eloisa,
BeltranMir Hector,
DoñateBuendía Carlos,
Andrés Juan,
Longo Elson
Publication year - 2019
Publication title -
particle and particle systems characterization
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.877
H-Index - 56
eISSN - 1521-4117
pISSN - 0934-0866
DOI - 10.1002/ppsc.201800533
Subject(s) - nucleation , materials science , irradiation , laser , femtosecond , nanoparticle , scanning electron microscope , analytical chemistry (journal) , nanostructure , spectroscopy , energy dispersive x ray spectroscopy , nanotechnology , optics , chemistry , physics , organic chemistry , chromatography , quantum mechanics , nuclear physics , composite material
In this work, for the first time, the instantaneous nucleation and growth processes of Ag nanoparticles on Ag 3 PO 4 mediated by femtosecond laser pulses are reported and analyzed. The investigated samples are pure Ag 3 PO 4 sample, electron‐irradiated Ag 3 PO 4 sample, and laser‐irradiated sample. Complete characterization of the samples is performed using X‐ray diffraction (XRD), Rietveld refinements, field emission scanning electron microscopy, and energy dispersive spectroscopy (EDS). XRD confirms that the irradiated surface layer remains crystalline, and according to EDS analysis, the surface particles are composed primarily of Ag nanoparticles. This method not only offers a one‐step route to synthesize Ag nanoparticles using laser‐assisted irradiation with particle size control, but also reports a complex process involving the formation and subsequent growth of Ag nanoparticles through an unexpected additive‐free in situ fabrication process.