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Synthesis and Characterization of a Novel Ternary Hematite Nanocomposites Structure with Fullerene and 2D‐Electrochemical Reduced Graphene Oxide for Superior Photoelectrochemical Performance
Author(s) -
Phuan Yi Wen,
Chong Meng Nan,
Satokhee Oodaye,
De Souza Andrew Brian,
Zhu Tao,
Chan Eng Seng
Publication year - 2017
Publication title -
particle and particle systems characterization
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.877
H-Index - 56
eISSN - 1521-4117
pISSN - 0934-0866
DOI - 10.1002/ppsc.201600216
Subject(s) - hematite , graphene , ternary operation , photocurrent , materials science , dielectric spectroscopy , oxide , nanocomposite , chemical engineering , electrochemistry , nanotechnology , optoelectronics , chemistry , electrode , computer science , engineering , metallurgy , programming language
In this study, a novel ternary hematite nanocomposites photoanode structure with superior photoelectrochemical (PEC) performance consisting of fullerene (C 60 ) and 2D‐electrochemical reduced graphene oxide (eRGO) used as the effective surface passivators is developed. The introduction of both the electron scavenging C 60 and highly conducting eRGO has mitigated the high interfacial recombination rate of hematite and led to the superior enhancement in PEC performance. UV–vis analysis reveals that the incorporation of C 60 and eRGO can provide a stronger light absorption at the visible light (400 nm < λ < 700 nm) and near infrared (IR) region (λ > 700 nm). Through the electrochemical impedance spectroscopy measurements, it can be concluded that the introduction of C 60 and eRGO onto hematite photoanode improves electron transfer and collection, reduces charge‐carrier recombination efficiency, and enhances PEC activity. The resultant ternary hematite photoanode structure exhibits 16.8‐fold enhancement in photocurrent density and 0.8‐fold reduction in charge transfer resistance when compared to the bare hematite structure only. This study has shown that the application of C 60 , 2D‐eRGO, or in combination as a ternary structure provides the plasmonic effect that can enhance the PEC performance in hematite photoanode structure.