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A High‐Performance Anode Material for Li‐Ion Batteries Based on a Vertically Aligned CNTs/NiCo 2 O 4 Core/Shell Structure
Author(s) -
Liu Wenwen,
Lu Congxiang,
Liang Kun,
Tay Beng Kang
Publication year - 2014
Publication title -
particle and particle systems characterization
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.877
H-Index - 56
eISSN - 1521-4117
pISSN - 0934-0866
DOI - 10.1002/ppsc.201400030
Subject(s) - materials science , anode , electrode , electrolyte , annealing (glass) , electrochemistry , carbon nanotube , chemical engineering , nanotechnology , conductivity , composite material , chemistry , engineering
3D vertically aligned carbon nanotubes (CNTs)/NiCo 2 O 4 core/shell structures are successfully synthesized as binder‐free anode materials for Li‐ion batteries (LIBs) via a facile electrochemical deposition method followed by subsequent annealing in air. The vertically aligned CNTs/NiCo 2 O 4 core/shell structures are used as binder‐free anode materials for LIBs and exhibit high and stable reversible capacity (1147.6 mAhg −1 at 100 mAg −1 ), excellent rate capability (712.9 mAh g −1 at 1000 mAg −1 ), and good cycle stability (no capacity fading over 200 cycles). The improved performance of these LIBs is attributed to the unique 3D vertically aligned CNTs/NiCo 2 O 4 core/shell structures, which support high electron conductivity, fast ion/electron transport in the electrode and at the electrolyte/electrode interface, and accommodate the volume change during cycling. Furthermore, the synthetic strategy presented can be easily extended to fabricate other metal oxides with a controlled core/shell structure, which may be a promising electrode material for high‐performance LIBs.