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Transmission Fluctuation Spectrometry with Spatial Correlation
Author(s) -
Shen Jianqi,
Riebel Ulrich,
Guo Xiaoai
Publication year - 2005
Publication title -
particle and particle systems characterization
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.877
H-Index - 56
eISSN - 1521-4117
pISSN - 0934-0866
DOI - 10.1002/ppsc.200400896
Subject(s) - transmission (telecommunications) , monolayer , particle (ecology) , beam (structure) , suspension (topology) , particle size , particle beam , optics , computational physics , materials science , physics , analytical chemistry (journal) , chemistry , molecular physics , biological system , nanotechnology , mathematics , chromatography , computer science , telecommunications , oceanography , homotopy , geology , pure mathematics , biology
Transmission fluctuation spectrometry (TFS) is being developed as a new method of particle size analysis. In the early approaches, the particle suspension was illuminated by one beam with finite beam diameter and the transmission signals underwent a process with variable spatial and/or temporal averaging and a subsequent nonlinear operation. The transmission fluctuations were obtained as a spectrum which included the information on particle size distribution and particle concentration. A new approach presented here employs two narrow parallel beams. While changing the beam separation, the transmission fluctuations of these two beams are expressed in terms of the expectancy of the transmission product (ETP). The analytical expression of the ETP through a monolayer is derived and the ETP of a 3‐dimensional suspension is formulated based on the layer model. The deviation between the transition functions of 3‐dimensional suspensions and monolayers is found to be affected by effects from particle overlapping and monolayer structure.