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On‐line Surface Area Measurement of Concentrated Slurries using low field spin‐lattice relaxation NMR
Author(s) -
Thoma Steven B.,
Smith Douglas M.,
Boughton John,
Davies Reg
Publication year - 1993
Publication title -
particle and particle systems characterization
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.877
H-Index - 56
eISSN - 1521-4117
pISSN - 0934-0866
DOI - 10.1002/ppsc.19930100506
Subject(s) - adsorption , aqueous solution , slurry , analytical chemistry (journal) , chemistry , spin–lattice relaxation , specific surface area , relaxation (psychology) , materials science , nuclear magnetic resonance , chromatography , organic chemistry , psychology , social psychology , physics , composite material , nuclear quadrupole resonance , catalysis
A method for the rapid on‐line determination of surface area and solids content in flowing concentrated slurries using low field NMR spin‐lattice relaxation measurements has been developed and demonstrated. The relationship between flow and spin‐lattice relaxation time ( T 1 ) of protons in water at 20 MHz was examined using aqueous copper sulfate solutions. The ability to measure surface area and solids concentration in both stagnant (stopped flow) and flowing systems via NMR was demonstrated using several different concentrated aqueous titania and glass slurries (20 to 80 weight percent) for which the dried powder surface area was previously determined via nitrogen adsorption/BET analysis and the solids content determined gravimetrically. Surface areas were also calculated from particle size analysis and found to vary by up to an order of magnitude from the adsorption and NMR results.