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Cuboid Cu(HBTC)(H 2 O) 3 synthesis via plasma pretreatment of trimesic acid solution
Author(s) -
Kanno Moriyuki,
Ito Tsuyohito,
Shimizu Yoshiki,
Terashima Kazuo
Publication year - 2021
Publication title -
plasma processes and polymers
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.644
H-Index - 74
eISSN - 1612-8869
pISSN - 1612-8850
DOI - 10.1002/ppap.202100047
Subject(s) - trimesic acid , cuboid , copper , materials science , polyvinylpyrrolidone , metal , plasma , metal ions in aqueous solution , crystallography , nuclear chemistry , chemistry , polymer chemistry , metallurgy , geometry , molecule , organic chemistry , mathematics , physics , quantum mechanics
Metal–organic frameworks (MOFs) have attracted considerable research attention in recent years, with the focus being on controlling their morphology for various applications. Cu(HBTC)(H 2 O) 3 , a one‐dimensional MOF, is constructed with a copper(II) ion and 1,3,5‐benzenetricarboxylic acid (H 3 BTC, trimesic acid). A two‐dimensional structure can be achieved by adding ethanol and polyvinylpyrrolidone during synthesis. In this study, its three‐dimensional cuboid Cu(HBTC)(H 2 O) structure was synthesized by plasma pretreatment of an H 3 BTC solution.