Condensation of chloromethanes and their binary systems with triphenylphosphine induced by low‐voltage discharges | Zendy

Bodrikov Ivan V. | Zendy; Titov Evgeniy Y. | Zendy; Subbotin Andrey Y. | Zendy; Grinvald Iosif I. | Zendy; Titov Dmitry Y. | Zendy; Razov Evgeny N. | Zendy

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Condensation of chloromethanes and their binary systems with triphenylphosphine induced by low‐voltage discharges

Author(s) -

Bodrikov Ivan V.,

Titov Evgeniy Y.,

Subbotin Andrey Y.,

Grinvald Iosif I.,

Titov Dmitry Y.,

Razov Evgeny N.

Publication year - 2020

Publication title -

plasma processes and polymers

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.644

H-Index - 74

eISSN - 1612-8869

pISSN - 1612-8850

DOI - 10.1002/ppap.201900247

Subject(s) - triphenylphosphine , chloromethane , chemistry , hydrogen , phase (matter) , condensation , chloride , inorganic chemistry , photochemistry , organic chemistry , catalysis , thermodynamics , physics

Solid structures of different shapes, hydrogen chloride, and a small number of liquid products are formed from chloromethanes (CH 2 Cl 2 and CHCl 3 ) and binary systems with triphenylphosphine (CH 2 Cl 2 + PPh 3 , CHCl 3 + PPh 3 , and CCl 4 + PPh 3 ) under the action of a liquid‐phase low‐voltage discharge (60‐V DC). It is observed that triphenylphosphine additives sharply increase the reactivity of CCl 4 . Besides, a quantum chemical simulation of chloromethane transformation mechanism in the binary systems with triphenylphosphine is conducted, together with the likely mechanism of chloromethane conversion into active particles under the action of a liquid‐phase low‐voltage pulsed discharge.

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