Premium
Fragmentation of thiophene and 3‐methyl‐2‐thiophenecarboxaldehyde by direct liquid phase low‐voltage discharges
Author(s) -
Bodrikov Ivan V.,
Kut'in Alexander M.,
Titov Evgeniy Yu,
Titov Dmitry Yu.,
Kurskii Yury A.,
Gazizullin Ramis R.
Publication year - 2018
Publication title -
plasma processes and polymers
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.644
H-Index - 74
eISSN - 1612-8869
pISSN - 1612-8850
DOI - 10.1002/ppap.201800094
Subject(s) - thiophene , acetylene , fragmentation (computing) , hydrogen , diacetylene , carbon disulfide , photochemistry , chemistry , materials science , soot , analytical chemistry (journal) , organic chemistry , polymer , polymerization , combustion , computer science , operating system
Thiophene and 3‐methyl‐2‐thiophenecarboxaldehyde conversion by direct liquid phase discharges has been experimentally studied. The voltage was limited to 40 V. The main products of conversion, determined by GC and GC‐MS methods, for thiophene were: acetylene, carbon disulfide, soot, and hydrogen; for 3‐methyl‐2‐thiophenecarboxaldehyde—carbon disulfide, acetylene, soot, carbon dioxide, hydrogen, and diacetylene. Schemes of fragmentation of these heterocyclic compounds under the action of low‐voltage discharges are proposed.