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Post‐synthesis Carbon Nanowalls Transformation under Hydrogen, Oxygen, Nitrogen, Tetrafluoroethane and Sulfur Hexafluoride Plasma Treatments
Author(s) -
Vizireanu Sorin,
Ionita Maria Daniela,
Dinescu Gheorghe,
Enculescu Ionut,
Baibarac Mihaela,
Baltog Ioan
Publication year - 2012
Publication title -
plasma processes and polymers
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.644
H-Index - 74
eISSN - 1612-8869
pISSN - 1612-8850
DOI - 10.1002/ppap.201100153
Subject(s) - surface modification , sulfur hexafluoride , wetting , chemical engineering , argon , fourier transform infrared spectroscopy , sulfur , nitrogen , carbon fibers , oxygen , materials science , superhydrophilicity , hydrogen , raman spectroscopy , fluorine , contact angle , chemistry , organic chemistry , composite material , composite number , metallurgy , physics , optics , engineering
Carbon nanowalls (CNWs) functionalization allows the tailoring of some of their properties after they have been synthesized. Herewith we report on post‐synthesis CNWs functionalization by plasma treatments. Radiofrequency plasmas generated in hydrogen, oxygen, nitrogen, tetrafluoroethane, and sulfur hexafluoride admixed to argon, were used. The changes of morphology, structure, chemical composition were determined by SEM, FTIR, Raman Spectroscopy, specifically for each gas mixture. The results point out to the surface erosion, the functional groups attachment, or to thin film coverage of CNWs material. Such processes strongly influence the material properties, as exemplified by the wettability: superhydrophilic or superhydrophobic surfaces are obtained starting from the same base CNWs material.

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