Premium
Hybrid Sputtering‐Remote PECVD Deposition of Au Nanoparticles on SiO 2 Layers for Surface Plasmon Resonance‐Based Colored Coatings
Author(s) -
Beyene Haile Takele,
Tichelaar Frans D.,
Peeters Paul,
Kolev Ivan,
van de Sanden Mauritius C. M.,
Creatore Mariadriana
Publication year - 2010
Publication title -
plasma processes and polymers
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.644
H-Index - 74
eISSN - 1612-8869
pISSN - 1612-8850
DOI - 10.1002/ppap.201000003
Subject(s) - hexamethyldisiloxane , materials science , surface plasmon resonance , nanoparticle , sputter deposition , plasma enhanced chemical vapor deposition , sputtering , surface plasmon , analytical chemistry (journal) , ellipsometry , deposition (geology) , localized surface plasmon , layer (electronics) , thin film , plasmon , optoelectronics , nanotechnology , plasma , chemistry , paleontology , physics , quantum mechanics , chromatography , sediment , biology
In this paper, a hybrid system consisting of metal nano‐particles dispersed on the surface of a dielectric layer is presented: a remote Expanding Thermal Plasma CVD system is used for the deposition of the inorganic (i.e. SiO 2 ) layers from hexamethyldisiloxane/oxygen mixtures in combination with an rf magnetron sputtering tool for the deposition of metallic (i.e. gold) nanoparticles on top of the SiO 2 layers. The optical properties of the Au/SiO 2 layers have been investigated by means of UV‐VIS‐NIR variable angle spectroscopic ellipsometry. Rutherford backscattering and transmission electron microscopy were used to determine the film density, the nanoparticle size and its distribution, respectively. The uniform distribution of gold nanoparticles on the surface of the SiO 2 layers allows obtaining red‐ to blue‐ colored coatings as a consequence of the shift of the surface plasmon resonance band to higher wavelengths, caused by an increase in size of nanoparticles and metal surface coverage.