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Rapid Hyperbranched Polythioether Synthesis Through Thiol‐Michael Addition Reaction
Author(s) -
Daglar Ozgun,
Gungor Begum,
Guric Gulce,
Gunay Ufuk Saim,
Hizal Gurkan,
Tunca Umit,
Durmaz Hakan
Publication year - 2020
Publication title -
journal of polymer science
Language(s) - English
Resource type - Journals
eISSN - 2642-4169
pISSN - 2642-4150
DOI - 10.1002/pol.20190279
Subject(s) - trimethylolpropane , monomer , gel permeation chromatography , polymer chemistry , chemistry , polymerization , thiol , michael reaction , catalysis , chloroform , polymer , chromatography , organic chemistry , polyurethane
In this study, two types of hyperbranched (HB) polythioether could readily be achieved in a short time at ambient temperature through a thiol‐Michael addition reaction. Dimethyl acetylenedicarboxylate (DMADC) or methyl propiolate (A 2 ) and trimethylolpropane tris(3‐mercaptopropionate) (B 3 ) monomers were reacted using an organobase 1,5,7‐triazabicyclo[4.4.0]dec‐5‐ene (TBD) as a catalyst in chloroform at room temperature to provide subsequent HB polythioethers. The effect of TBD concentration on the polymerization was studied for the DMDAC case monitoring the molecular weight evolution against time. HB polythioethers were characterized using spectroscopic (nuclear magnetic resonance) and chromatographic (gel permeation chromatography with refractive index and light‐scattering detectors) techniques. © 2020 Wiley Periodicals, Inc. J. Polym. Sci. 2020 , 58 , 824–830