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Dynamics and reactivity of chiral ion–dipole pairs
Author(s) -
Speranza Maurizio
Publication year - 2005
Publication title -
journal of physical organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.325
H-Index - 66
eISSN - 1099-1395
pISSN - 0894-3230
DOI - 10.1002/poc.860
Subject(s) - chemistry , reactivity (psychology) , dipole , chemical physics , ion , computational chemistry , ionic bonding , adduct , ionic liquid , solvent , molecular dynamics , organic chemistry , catalysis , medicine , alternative medicine , pathology
Modeling ionic reactions in a dynamic environment, such as in a solvent cage, requires the generation of tailor‐made ionic adducts involved in the process and the investigation of the intrinsic structural and electronic factors governing their behavior in the unsolvated state. A compendium of the most recent studies on the gas‐phase dynamics and reactivity of chiral ion–dipole pairs involved in classical organic reactions is reported, together with a presentation of the experimental and theoretical methodologies adopted. Copyright © 2004 John Wiley & Sons, Ltd.