Dynamics and reactivity of chiral ion–dipole pairs | Zendy

Speranza Maurizio | Zendy

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Dynamics and reactivity of chiral ion–dipole pairs

Author(s) -

Speranza Maurizio

Publication year - 2005

Publication title -

journal of physical organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.325

H-Index - 66

eISSN - 1099-1395

pISSN - 0894-3230

DOI - 10.1002/poc.860

Subject(s) - chemistry , reactivity (psychology) , dipole , chemical physics , ion , computational chemistry , ionic bonding , adduct , ionic liquid , solvent , molecular dynamics , organic chemistry , catalysis , medicine , alternative medicine , pathology

Modeling ionic reactions in a dynamic environment, such as in a solvent cage, requires the generation of tailor‐made ionic adducts involved in the process and the investigation of the intrinsic structural and electronic factors governing their behavior in the unsolvated state. A compendium of the most recent studies on the gas‐phase dynamics and reactivity of chiral ion–dipole pairs involved in classical organic reactions is reported, together with a presentation of the experimental and theoretical methodologies adopted. Copyright © 2004 John Wiley & Sons, Ltd.

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