Stabilization of benzene versus oligoacetylenes: not another scale for aromaticity | Zendy

Baldridge Kim K. | Zendy; Siegel Jay S. | Zendy

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Stabilization of benzene versus oligoacetylenes: not another scale for aromaticity

Author(s) -

Baldridge Kim K.,

Siegel Jay S.

Publication year - 2004

Publication title -

journal of physical organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.325

H-Index - 66

eISSN - 1099-1395

pISSN - 0894-3230

DOI - 10.1002/poc.819

Subject(s) - aromaticity , chemistry , benzene , conjugated system , computational chemistry , perspective (graphical) , benzene derivatives , scale (ratio) , organic chemistry , molecule , quantum mechanics , artificial intelligence , biochemistry , chemical synthesis , computer science , in vitro , polymer , physics

The energies of a number of oligoacetylenes are compared in a homodesmic reaction with benzene. Assessment of the open vs closed form of a conjugated triene is presented along with a perspective on the pursuit of quantitative scales for ‘aromaticity’. Copyright © 2004 John Wiley & Sons, Ltd.

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