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Converting the role of LiClO 4 from salting‐in to salting‐out in Diels–Alder reactions by solvent manipulation
Author(s) -
Deshpande Suvarna S.,
Pawar Sanjay S.,
Phalgune Usha,
Kumar Anil
Publication year - 2003
Publication title -
journal of physical organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.325
H-Index - 66
eISSN - 1099-1395
pISSN - 0894-3230
DOI - 10.1002/poc.668
Subject(s) - chemistry , solvent , yield (engineering) , diels–alder reaction , salt (chemistry) , aqueous solution , salting out , salting , organic chemistry , alder , catalysis , thermodynamics , food science , ecology , physics , biology
Abstract The low yield of endo products of a Diels–Alder reaction in aqueous LiClO 4 can be enhanced by using a simple solvent manipulation. This report on the use of salt solutions opens up the possibility of creating effective conditions for Diels–Alder reactions. Copyright © 2003 John Wiley & Sons, Ltd.