Converting the role of LiClO 4  from salting‐in to salting‐out in Diels–Alder reactions by solvent manipulation | Zendy

Deshpande Suvarna S. | Zendy; Pawar Sanjay S. | Zendy; Phalgune Usha | Zendy; Kumar Anil | Zendy

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Converting the role of LiClO 4 from salting‐in to salting‐out in Diels–Alder reactions by solvent manipulation

Author(s) -

Deshpande Suvarna S.,

Pawar Sanjay S.,

Phalgune Usha,

Kumar Anil

Publication year - 2003

Publication title -

journal of physical organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.325

H-Index - 66

eISSN - 1099-1395

pISSN - 0894-3230

DOI - 10.1002/poc.668

Subject(s) - chemistry , solvent , yield (engineering) , diels–alder reaction , salt (chemistry) , aqueous solution , salting out , salting , organic chemistry , alder , catalysis , thermodynamics , food science , ecology , physics , biology

The low yield of endo products of a Diels–Alder reaction in aqueous LiClO 4 can be enhanced by using a simple solvent manipulation. This report on the use of salt solutions opens up the possibility of creating effective conditions for Diels–Alder reactions. Copyright © 2003 John Wiley & Sons, Ltd.

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