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The search for the ethynylcation: Nitrosation of N , N ‐bis(trimethylsilyl)ynamines
Author(s) -
Alvarez Roberto Martínez,
Hanack Michael,
Schmid Thomas,
Subramanian L. R.
Publication year - 1995
Publication title -
journal of physical organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.325
H-Index - 66
eISSN - 1099-1395
pISSN - 0894-3230
DOI - 10.1002/poc.610080310
Subject(s) - chemistry , nitrosation , trimethylsilyl , organic chemistry , medicinal chemistry , computational chemistry
The reaction of bis‐silylated ynamines with different nitrosyl reagents affords products derived from an electrophilic attack at the β‐carbon atom and not the expected alkynyldiazonium salts.