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Kinetics of the reaction of amines with 1,1,1‐trichloro‐4‐methoxy‐3‐penten‐2‐one
Author(s) -
Gesser José Carlos,
Zucco César,
Nome Faruk
Publication year - 1995
Publication title -
journal of physical organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.325
H-Index - 66
eISSN - 1099-1395
pISSN - 0894-3230
DOI - 10.1002/poc.610080208
Subject(s) - chemistry , toluene , chloroform , methanol , kinetics , ethanol , hexane , organic chemistry , medicinal chemistry , quantum mechanics , physics
The kinetics of the reaction of 1,1,1‐trichloro‐4‐methoxy‐3‐penten‐2‐one with various aliphatic and aromatic amines was studied at 25°C in water, dimethyl sulphoxide, methanol, ethanol, chloroform, toluene and hexane. The formation of the corresponding 1,1,1‐trichloro‐4‐amino‐3‐penten‐2‐one is explained in terms of an addition–elimination mechanism.