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Variation of ρ x (ρ nuc ) with the extent of bond making in S N 2 transition states
Author(s) -
Lee Ikchoon,
Koh Han Joong,
Lee Byung Choon
Publication year - 1994
Publication title -
journal of physical organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.325
H-Index - 66
eISSN - 1099-1395
pISSN - 0894-3230
DOI - 10.1002/poc.610070109
Subject(s) - chemistry , acetonitrile , kinetic isotope effect , isotope , kinetic energy , variation (astronomy) , transition state , organic chemistry , deuterium , atomic physics , catalysis , nuclear physics , astrophysics , physics , quantum mechanics
The magnitude ρx(ρ nuc ) is shown to decrease with increase in the extent of bond making estimated by the kinetic isotope effect for the reactions of Y‐benzoyl chlorides with anilines, XC 6 H 4 NH 2 , in acetonitrile at 25·0°C.