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First determination of an absolute rate constant for a 1,2‐phenyl migration to a carbene
Author(s) -
Liu Michael T. H.
Publication year - 1993
Publication title -
journal of physical organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.325
H-Index - 66
eISSN - 1099-1395
pISSN - 0894-3230
DOI - 10.1002/poc.610061207
Subject(s) - chemistry , carbene , flash photolysis , nanosecond , flash (photography) , reaction rate constant , photochemistry , constant (computer programming) , laser , absolute (philosophy) , photodissociation , computational chemistry , organic chemistry , kinetics , optics , catalysis , philosophy , physics , epistemology , computer science , programming language , quantum mechanics
The first determination of a 1,2‐phenyl shift in α,α‐dimethylbenzylchlorocarbene was achieved by nanosecond laser flash photolysis, τ = 50 ns.
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