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π‐Complexes of naphthalene and its derivatives with nitrosonium cation
Author(s) -
Borodkin Gennady I.,
Elanov Innokenty R.,
Shakirov Makhmut M.,
Shubin Vyacheslav G.
Publication year - 1993
Publication title -
journal of physical organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.325
H-Index - 66
eISSN - 1099-1395
pISSN - 0894-3230
DOI - 10.1002/poc.610060305
Subject(s) - chemistry , naphthalene , deuterium , computational chemistry , organic chemistry , polymer chemistry , quantum mechanics , physics
1 H, 13 C, and 15 N NMR studies, including the use of the 13 C NMR deuterium perturbation method, showed that the interaction between naphthalene or its methylated derivatives and the nitrosonium cation result in the formation of π‐complexes. The chemical behaviour of these complexes was investigated; in particular, their ability to be converted into binaphthyl derivatives was established.