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Quantitative aspects of chirality. II. Analysis of dissymmetry function behaviour with different changes in the structure of the model systems
Author(s) -
Kuz'min V. E.,
Stel'makh I. B.,
Yudanova I. V.,
Pozigun D. V.,
Bekker M. B.
Publication year - 1992
Publication title -
journal of physical organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.325
H-Index - 66
eISSN - 1099-1395
pISSN - 0894-3230
DOI - 10.1002/poc.610050604
Subject(s) - chemistry , polyhedron , tetrahedron , chirality (physics) , valence (chemistry) , function (biology) , valence bond theory , computational chemistry , crystallography , chemical physics , molecule , chiral symmetry , geometry , organic chemistry , quantum mechanics , physics , molecular orbital , mathematics , evolutionary biology , nambu–jona lasinio model , biology , quark
The efficiency of the developed method of dissymmetry functions was studied using various model systems. The alteration of the dissymmetry function was analysed with systematic variations of the bond lengths, valence angles and masses of atoms in model tetrahedra. The behaviour of the dissymmetry function was studied for conformationally labile systems and chiral polyhedra. In general, it was found that in all cases the alteration of the dissymmetry function is in agreement with the speculative representations of the changes in degree of chirality.