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Cyclopropylmethoxycarbene: A kinetic limit on the 1,2‐carbon migration
Author(s) -
Moss Robert A.,
Jang Eun G.,
Fan Hong,
Włostowski Marek,
KroghJespersen Karsten
Publication year - 1992
Publication title -
journal of physical organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.325
H-Index - 66
eISSN - 1099-1395
pISSN - 0894-3230
DOI - 10.1002/poc.610050207
Subject(s) - chemistry , kinetic energy , limit (mathematics) , carbon fibers , computational chemistry , classical mechanics , mathematical analysis , composite number , physics , materials science , mathematics , composite material
Cyclopropylmethoxycarbene undergoes ambiphilic‐nucleophilic intermolecular reaction with alkenes and methanol, but its intramolecular chemistry (1,2‐carbon migration) is suppressed ( k < 3 × 10 3 s −1 ) by the α‐methoxy substituent.
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