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Topological aspects of chemical reactivity. Evans–dewar principle in terms of molecular similarity approach
Author(s) -
Ponec Robert,
Strnad Martin
Publication year - 1991
Publication title -
journal of physical organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.325
H-Index - 66
eISSN - 1099-1395
pISSN - 0894-3230
DOI - 10.1002/poc.610041109
Subject(s) - chemistry , similarity (geometry) , reactivity (psychology) , simple (philosophy) , computational chemistry , legitimacy , topology (electrical circuits) , theoretical physics , epistemology , artificial intelligence , computer science , physics , philosophy , politics , political science , law , medicine , alternative medicine , mathematics , pathology , combinatorics , image (mathematics)
The Evans‐Dewar concept of aromaticity of transition states is given new theoretical support in terms of the similarity approach to chemical reactivity. The principal goal of this approach consists in providing a simple, chemically lucid justification for the legitimacy of the original intuitively formulated concept.