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The decay of 2‐phenyl‐1,3‐dioxolane‐2‐ylium salts in solution
Author(s) -
Spange Stefan,
Heublein Günther,
Schütz Heidrun,
Lukaszcyk Jan,
Jedlinsky Zbigniew
Publication year - 1990
Publication title -
journal of physical organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.325
H-Index - 66
eISSN - 1099-1395
pISSN - 0894-3230
DOI - 10.1002/poc.610030309
Subject(s) - chemistry , dioxolane , 1,2 dichloroethane , dichloroethane , spectroscopy , ion , inorganic chemistry , medicinal chemistry , nuclear magnetic resonance spectroscopy , organic chemistry , catalysis , physics , quantum mechanics
The decay of 2‐phenyl‐1,3‐dioxolane‐2‐ylium salts in 1,2‐dichloroethane solution has been studied by means of 1 H NMR and UV spectroscopy and conductimetry. The influence of the nature of the anion (SbCl 6 − , SbCl 5 Br − , AsF 6 − ) and of the methyl substituents on the rate constants of decay is discussed.