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Stereochemistry of silver‐ion‐assisted solvolysis of tert ‐butylphenylphosphinothioic iodidate. Phosphathiacylium cation formation
Author(s) -
Skrzypczyński Zbigniew
Publication year - 1990
Publication title -
journal of physical organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.325
H-Index - 66
eISSN - 1099-1395
pISSN - 0894-3230
DOI - 10.1002/poc.610030107
Subject(s) - solvolysis , chemistry , ion , silver salts , reactive intermediate , optically active , walden inversion , phosphorus , stereochemistry , inorganic chemistry , medicinal chemistry , photochemistry , computational chemistry , organic chemistry , hydrolysis , catalysis
Studies on the stereochemistry of silver‐ion‐assisted solvolysis of a new optically active tert ‐butylphenylphosphinothioic iodidate demonstrated that the reaction proceeds with inversion of configuration at the phosphorus atom. Evidence for phosphathiacylium cation formation as a reactive intermediate is presented.