Stereochemistry of silver‐ion‐assisted solvolysis of  tert ‐butylphenylphosphinothioic iodidate. Phosphathiacylium cation formation | Zendy

Skrzypczyński Zbigniew | Zendy

Premium

Stereochemistry of silver‐ion‐assisted solvolysis of tert ‐butylphenylphosphinothioic iodidate. Phosphathiacylium cation formation

Author(s) -

Skrzypczyński Zbigniew

Publication year - 1990

Publication title -

journal of physical organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.325

H-Index - 66

eISSN - 1099-1395

pISSN - 0894-3230

DOI - 10.1002/poc.610030107

Subject(s) - solvolysis , chemistry , ion , silver salts , reactive intermediate , optically active , walden inversion , phosphorus , stereochemistry , inorganic chemistry , medicinal chemistry , photochemistry , computational chemistry , organic chemistry , hydrolysis , catalysis

Studies on the stereochemistry of silver‐ion‐assisted solvolysis of a new optically active tert ‐butylphenylphosphinothioic iodidate demonstrated that the reaction proceeds with inversion of configuration at the phosphorus atom. Evidence for phosphathiacylium cation formation as a reactive intermediate is presented.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research