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Circular dichroism of In ‐ Situ trinuclear organotransition metal complexes with optically active ligands
Author(s) -
Barton Derek H. R.,
Frelek Jadwiga,
Snatzke Günther
Publication year - 1988
Publication title -
journal of physical organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.325
H-Index - 66
eISSN - 1099-1395
pISSN - 0894-3230
DOI - 10.1002/poc.610010106
Subject(s) - chemistry , circular dichroism , optically active , in situ , metal , cotton effect , absorption (acoustics) , nitrogen , stereochemistry , photochemistry , crystallography , organic chemistry , optics , physics
Several Cotton effects are developed within absorption bands of trinuclear organotransitionmetal complexes in the presence of acids, diols, amines and aminoalcohols even in the case of bulky substituents on nitrogen; with monohydroxy compounds no circular dichroism could be detected.