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Structure of radical intermediates appearing in the grignard reaction of monoketones
Author(s) -
Maruyama Kazuhiro,
Katagiri Toshimasa
Publication year - 1988
Publication title -
journal of physical organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.325
H-Index - 66
eISSN - 1099-1395
pISSN - 0894-3230
DOI - 10.1002/poc.610010104
Subject(s) - chemistry , radical ion , reaction intermediate , photochemistry , radical cyclization , radical , ion , reactive intermediate , radical nucleophilic aromatic substitution , medicinal chemistry , organic chemistry , catalysis , nucleophilic substitution , nucleophilic aromatic substitution
The structure of radical intermediates appearing in the reactions of MeMgBr with aromatic monoketones was investigated by using ESR and visible spectroscopy. Stable radical intermediates in the reacting solutions were assigned to the dimeric radical ion pairs.