Structure–reactivity correlation for the ligand‐decelerated catalytic osmium tetraoxide dihydroxylation of alkenes | Zendy

Erdik Ender | Zendy; Kâhya Didem | Zendy

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Structure–reactivity correlation for the ligand‐decelerated catalytic osmium tetraoxide dihydroxylation of alkenes

Author(s) -

Erdik Ender,

Kâhya Didem

Publication year - 2002

Publication title -

journal of physical organic chemistry

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.325

H-Index - 66

eISSN - 1099-1395

pISSN - 0894-3230

DOI - 10.1002/poc.475

Subject(s) - chemistry , osmium , dihydroxylation , ligand (biochemistry) , catalysis , reactivity (psychology) , pyridine , medicinal chemistry , organic chemistry , photochemistry , enantioselective synthesis , ruthenium , medicine , biochemistry , receptor , alternative medicine , pathology

Kinetic studies on the ligand‐decelerated catalytic OsO 4 dihydroxylation of seven substituted styrenes with trimethylamine‐ N ‐oxide in the absence and in the presence of pyridine ligand have been carried out. The rates correlate with the Hammett relationship and V‐shaped plots with a maximum are in agreement with the oxidation of osmate(VI) ester in the rate‐determining step. Copyright © 2002 John Wiley & Sons, Ltd.

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