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Quantum chemical design of near‐infrared sensitive fused ring electron acceptors containing selenophene as π‐bridge for high‐performance organic solar cells
Author(s) -
Mehboob Muhammad Yasir,
Hussain Riaz,
Khan Muhammad Usman,
Adnan Muhammad,
Ehsan Muhammad Ali,
Rehman Abdul,
Janjua Muhammad Ramzan Saeed Ashraf
Publication year - 2021
Publication title -
journal of physical organic chemistry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.325
H-Index - 66
eISSN - 1099-1395
pISSN - 0894-3230
DOI - 10.1002/poc.4204
Subject(s) - organic solar cell , chemistry , photocurrent , density functional theory , homo/lumo , electron acceptor , molecule , acceptor , absorption (acoustics) , time dependent density functional theory , photochemistry , molecular orbital , absorption spectroscopy , computational chemistry , chemical physics , optoelectronics , materials science , organic chemistry , physics , quantum mechanics , condensed matter physics , polymer , composite material
End‐capped acceptors modification of fused ring electron acceptors (FREAs) is an attractive strategy to boost the optoelectronic and photovoltaic properties of the materials. FREAs are also proven beneficial due to their tremendous applications in organic solar cells (OSCs). Among fused‐ring electronic species, small fullerene‐free FREAs have already been drawn more attention due to their near‐infrared sensitivity and constantly increasing efficiencies. Therefore, we have designed six new FREAs ( K1–K6 ) having selenophene as π‐bridge in between the central alkylated indaceno[1,2‐ b :5,6 b ]dithiophene (IDT) unit after the incorporations of various end‐capped acceptors on to the recently synthesized IDT2SeC2C4‐4F molecule. Structural–property relationship and photophysical and photovoltaic properties of newly designed molecules are studied with the help of density functional theory (DFT) and time‐dependent DFT (TD‐DFT). Certain critical specifications like frontier molecular orbitals (FMOs) alignment, density of states (DOS), absorption maxima, excitation energy, binding energy (BE) along with transition density matrix (TDM), and the specifically estimated reorganizational energy values of electron and hole and the open circuit voltages of newly designed molecules are computed and compared with reference molecule. Generally, a red‐shifting absorption behavior of FREAs is considered the most important reason for their high efficiencies in OSCs. Our novel designed molecules exhibit red shift in absorption spectrum. Similarly, low excitation and binding energies of designed molecules offer improved power conversion efficiencies (PCEs) with highest possible charge photocurrent density ( J sc ) in OSCs devices. Furthermore, study of PTB7‐Th/K1 complex is also done in order to examine charge transfer between within complex. By introducing the efficient end‐capped acceptor moieties in reference molecule, enhancement in charge mobilities is noted. The large open circuit voltage, low reorganizational energies, narrower highest occupied molecular orbital–lowest unoccupied molecular orbital (HOMO–LUMO) energy gap, lower binding and excitation energies, and highly red shifting in absorption phenomenon indicate an efficient designing of molecules, which could be best fitted for high efficiency OSCs. Finally, theorized molecules are much superior related to their photovoltaic and electronic properties and thus are recommended to experimentalist for their synthesis and out‐looking future developments of highly efficient solar cells devices.